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    基于绝对反应速率理论的PMMA/MMA溶液的黏度

    Viscosity of PMMA/MMA Solutions Based on Absolute Reaction Rate Theory

    • 摘要: 基于Eyring的绝对反应速率理论研究了聚甲基丙烯酸甲酯(PMMA)/甲基丙烯酸甲酯(MMA)溶液在不同温度、不同浓度下的黏度,讨论了聚合物溶液黏性流动活化能与溶液中聚合物质量分数以及聚合物分子量的关系。最后通过拟合得出聚合物溶液的黏度与温度,溶液的浓度以及聚合物分子量的关联式。通过此模型计算出的黏度数值与文献值吻合良好。

       

      Abstract: Viscosity of solutions of polymethyl (methacrylate)(PMMA) in methyl methacrylate (MMA) at different temperatures and concentrations was investigated by the absolute rate theory proposed by Eyring. The dependences of activation energy for flowing of the polymer solutions on the solution concentration and the molecular weight of the polymer were examined. The dependences of the solution viscosity on the concentration, molecular weight and temperature were approximated by a semi empirical equation. The viscosity calculated from the model agreed well with the value from literature.

       

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