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    纳米颗粒与表面活性剂协同稳定C/W乳液及其耐盐性

    Synergistic Stabilization of C/W Emulsions by Nanoparticles and Surfactants and Their Salt Resistance

    • 摘要: 采用椰油酰胺丙基甜菜碱(CAPB)与纳米二氧化硅(SiO2)颗粒协同稳定高内相CO2/水(C/W)乳液,测定了乳液的半衰期、表观黏度和界面张力,考察了纳米颗粒质量分数、盐离子种类以及矿化度对乳液稳定性的影响,并将该乳液应用于驱替模拟油的实验。结果表明,CAPB(wCAPB=4.00%)单独稳定乳液的半衰期为4.60 h,驱替效率为70.33%;纳米SiO2颗粒(w_\mathrmSiO_2 =0.70%)与CAPB(wCAPB=4.00%)协同稳定乳液的半衰期为21.92 h,驱替效率为77.61%;在w_\mathrmNa^+ =7.00%时,CAPB(wCAPB=4.00%)单独稳定的乳液可稳定4.04 h,SiO2与CAPB协同稳定的乳液可稳定15.24 h;在w_\mathrmCa^2+ =0.05%时,单独稳定时间为4.37 h,协同稳定时间为13.20 h;在矿化度为1×104 mg/L时,协同稳定时间能达17.88 h,驱替采收率达55.98%。SiO2与CAPB协同稳定的乳液体系能够提高模拟油驱替的采收率。

       

      Abstract: High internal phase CO2-in-water emulsions (C/W) were stabilized with cocamidopropyl betaine (CAPB) and nano-SiO2 particles. The half-life, apparent viscosity, and interfacial tension of the emulsion were measured. The effects of the concentration of nanoparticles, the type of salt ions and the degree of salinity on the stability of the emulsion were investigated. The results indicated that the half life and displacement efficiency of the emulsions constructed by CAPB (wCAPB=4.00%) were 4.60 h and 70.33%, respectively. The half-life of the emulsions synergistically by nano-SiO2 (w_\mathrmSiO_2 =0.70%) particles and CAPB (wCAPB=4.00%) was 21.92 h, and the displacement efficiency was 77.61%. When the mass fraction of Na+ was 7.00%, the former could be stable for 4.04 h, while the latter for 15.24 h. When the mass fraction of Ca2+ was 0.05%, the former could be stable for 4.37 h, while the latter for 13.20 h. When the salinity was 1×104 mg/L, the latter emulsion could remain stable for 17.88 h, and the displacement efficiency reached 55.98%. In conclusion, CAPB mainly plays a role in the formation of emulsions, while SiO2 mainly improves the stability of emulsions. The emulsion system stabilized by SiO2 and CAPB can improve the simulated oil displacement recovery.

       

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