Ring Opening Metathesis Polymerisation of Dicyclopentadiene\=Catalysed by Titanium
Tetracloride Adduct Complexes\=Containing Nitrogen or Oxygen Ligand
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Graphical Abstract
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Abstract
The ring opening metathesis polymerisation of
dicyclopentadiene (DCPD) catalysed by TiCl42 ( 1 ):TiCl4211N( 2 );TiCl42 ( 3 );TiCl42 ( 4 );TiCl42
(5 );TiCl42 ( 6Z) is reported.These catalysis appear to exhibit good catalytic activity in the
polymerisation reaction.After a detailed investigation of some influencing parameters,the
optimised reaction conditions were obtained.
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