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    庄炜杰, 仇鹏, 曾泽李, 代正华, 王辅臣. 甲烷催化双重整过程模拟[J]. 华东理工大学学报(自然科学版), 2022, 48(3): 290-296. DOI: 10.14135/j.cnki.1006-3080.20210313004
    引用本文: 庄炜杰, 仇鹏, 曾泽李, 代正华, 王辅臣. 甲烷催化双重整过程模拟[J]. 华东理工大学学报(自然科学版), 2022, 48(3): 290-296. DOI: 10.14135/j.cnki.1006-3080.20210313004
    ZHUANG Weijie, QIU Peng, ZENG Zeli, DAI Zhenghua, WANG Fuchen. Simulation of Methane Catalytic Bi-Reforming Process[J]. Journal of East China University of Science and Technology, 2022, 48(3): 290-296. DOI: 10.14135/j.cnki.1006-3080.20210313004
    Citation: ZHUANG Weijie, QIU Peng, ZENG Zeli, DAI Zhenghua, WANG Fuchen. Simulation of Methane Catalytic Bi-Reforming Process[J]. Journal of East China University of Science and Technology, 2022, 48(3): 290-296. DOI: 10.14135/j.cnki.1006-3080.20210313004

    甲烷催化双重整过程模拟

    Simulation of Methane Catalytic Bi-Reforming Process

    • 摘要: 以甲烷重整转化炉为研究对象,基于动力学模型,考察了温度、压力与进料物质的量之比对甲烷双重整反应过程的影响。结果表明:在压力3.2 MPa下,甲烷、水蒸气与二氧化碳的转化率均随温度的升高而增大。与甲烷水蒸气重整反应相比,甲烷二氧化碳重整反应的反应温度更高,二氧化碳于650 ℃开始进行转化。随着压力的增大,甲烷、水蒸气和二氧化碳的转化率都快速下降。当压力达到3.5 MPa时,甲烷、水蒸气与二氧化碳的转化率均小于40%,但压力对氢气与一氧化碳的物质的量之比的影响不明显。反应体系中二氧化碳的增加有利于提高甲烷转化率,但会使水蒸气转化率大幅度降低。 因此可以通过调节温度和进料中水蒸气和二氧化碳的物质的量之比来调整反应产物中氢气与一氧化碳的物质的量之比。

       

      Abstract: The effects of temperature, pressure and feed ratio on a CH4 reformer were studied based on a kinetic model. The conversion rates of CH4, H2O and CO2 all increased with the increase of temperature at p=3.2 MPa. Compared with the steam reforming of CH4, the reaction temperature of CH4 and CO2 reforming was higher and CO2 began to transform at 650 ℃. The effect of temperature on the reaction rate of dry reforming of CH4 was considerable with a relatively high reaction temperature and pressure. With the increase of pressure, the conversion rates of CH4, H2O and CO2 decreased rapidly. When the pressure reached 3.5 MPa, the conversion rates of CH4, H2O and CO2 reduced to less than 40%. However, the influence of pressure on n(H2)∶n(CO) was minimal. The increase of CO2 in the reaction system was beneficial for improving the conversion rate of CH4, but significantly reduced the conversion rate of H2O at p=3.2 MPa. CO2 conversion was enhanced rapidly at first and then remained stable with the increase of n(CO2)∶n(CH4). CH4 and H2O conversion were both increased with the increase of n(H2O)∶n(CH4). The results show that n(H2)∶n(CO) can be optimized by adjusting the temperature and the relative concentration of H2O and CO2 in the feed gas to facilitate the subsequent industrialization.

       

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