Abstract:
Using
59Co as the simulated radioactive isotopes, the removal of Co
2+ from the simulated radioactive wastewater with boric acid in nuclear power plant by
in-situ synthesis of Mn
3O
4 was studied. The effects of reaction time,
n(Mn
2+):
n(Co
2+), air flow, reaction temperature and pH on the Co
2+ concentration in the effluent were investigated. An orthogonal experiment table L
9(4
3) was used to optimize the process parameters. When the wastewater contained 10 mg/L Co
2+ and 1 000 mg/L boric acid (as B), the optimal process was as follows: the reaction time 105 min,
n(Mn
2+):
n(Co
2+)=25: 1, air flow 0. 7 L/min, reaction temperature 65 ℃ and pH 10. 5. Under the optimal condition, the effluent concentration of Co
2+ was 5. 68 ng/L, the removal rate was more than 99. 99%. XRD analysis proved that the sediment was the mixture of Mn
3O
4 and CoMn
2O
4.