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    张万斌, 汪巩, 黄德音. 表面活性剂的合成及性能研究 Ⅱ.植物油脂肪酸烷基醇酰胺硫酸酯盐[J]. 华东理工大学学报(自然科学版), 1991, (4).
    引用本文: 张万斌, 汪巩, 黄德音. 表面活性剂的合成及性能研究 Ⅱ.植物油脂肪酸烷基醇酰胺硫酸酯盐[J]. 华东理工大学学报(自然科学版), 1991, (4).

    表面活性剂的合成及性能研究 Ⅱ.植物油脂肪酸烷基醇酰胺硫酸酯盐

    • 摘要: 以甲醇钠为催化剂,将椰子油和米糠油脂肪酸甲酯与乙醇胺反应,合成了两种脂肪酸烷基醇酰胺中间体。再用氯磺酸酯化、用氢氧化钠中和,得到两种文题产品(Ⅰ和Ⅱ)。产品的红外光谱数据与其结构的各特征吸收峰相符。测定了产品的克拉夫特点、发泡力和钙皂分散力,发现两种产品均具有较好的发泡性能和钙皂分散性能。用吸光度法对Ⅱ与肥皂复配体系的抗硬水能力进行了研究,得到了最佳复配比例。

       

      Abstract: Two products of sulfated alkanolamides from vegetable oils such as coconut oil and rice bran oil were prepared by the sodium methoxide catalyzed reaction of methyl esters of fatty acids with alkylolamines, the sulfation of the alkanolamides with chlorosulfonic acid and the nutrolization of the sulfated products with sodium hydroxide. The properties of the two products were measured and the results showed that they have low Krafft point, good foam height and lime soap dispersing power. The turbidities as a function of water hardness for the mixture of soap with the sulfated alkanolamide were also investigated and the best ratio of the two components in the mixture was found.

       

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