丁炔二醇合成反应的颗粒宏观动力学及选择性的研究
The investigation on the macrokinetics and selectivities of the butynediol synthesis reaction
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摘要: 本文从理论上分析了均匀分布有金属铜的球形大颗粒催化剂对合成丁炔二醇并-串连反应的影响,並用转框式反应器检验了宏观动力学分析结果。各组分浓度变化的模型计算值与实验测定值的相对误差一般在5%以内。Abstract: The influences of macrokinetic behaviors of spherical catalyst pellet with uniformly distributed copper content on the series-parrallel butynediol synthesis reaction have been studied. Some macrokinetic determinations have been performed to identify the above results by using a rotating basket reactor. The errors between the predicted and measured concentrations are less than 5 percent.