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    张舸, 金艳, 李丽, 韩昫身, 高荔, 于建国. 电催化氧化脱除气田采出水中硫化物[J]. 华东理工大学学报(自然科学版), 2022, 48(5): 565-575. DOI: 10.14135/j.cnki.1006-3080.20210609003
    引用本文: 张舸, 金艳, 李丽, 韩昫身, 高荔, 于建国. 电催化氧化脱除气田采出水中硫化物[J]. 华东理工大学学报(自然科学版), 2022, 48(5): 565-575. DOI: 10.14135/j.cnki.1006-3080.20210609003
    ZHANG Ge, JIN Yan, LI Li, HAN Xushen, GAO Li, YU Jianguo. Removing Sulfide in Gas Field Produced Water by Electrooxidation[J]. Journal of East China University of Science and Technology, 2022, 48(5): 565-575. DOI: 10.14135/j.cnki.1006-3080.20210609003
    Citation: ZHANG Ge, JIN Yan, LI Li, HAN Xushen, GAO Li, YU Jianguo. Removing Sulfide in Gas Field Produced Water by Electrooxidation[J]. Journal of East China University of Science and Technology, 2022, 48(5): 565-575. DOI: 10.14135/j.cnki.1006-3080.20210609003

    电催化氧化脱除气田采出水中硫化物

    Removing Sulfide in Gas Field Produced Water by Electrooxidation

    • 摘要: 采用污染小、效率高的电化学氧化法对高盐度、高硬度气田采出水的脱硫过程进行研究。选用Ti/RuO2-SnO2-IrO2阳极材料,在极板间距为5 cm、电流密度为200 A/m2、曝气量为1 L/min、初始pH为9~10的条件下,对模拟气田采出水(硫化物质量浓度为300 mg/L,NaCl质量分数为2.50%)处理35 min后,脱硫率高达99.2%以上,平均单位能耗为55.2 kW·h/kg(以每千克S2−计,全文同)。研究还发现,针对高硬度体系下的阴极结垢问题,利用倒极方法可有效去除结垢物,保证装置稳定运行。

       

      Abstract: Certain amounts of sulfide are present in gas field produced water, which brings negative effects on the environment and human health. Since the electrochemical oxidation method has the advantages of high efficiency without secondary pollution, we introduce it into the sulfide removal process under the conditions of high salinity and hardness. Based on the cyclic voltammetry characteristics, sulfide removal efficiency, and economic analysis, Ti/RuO2-SnO2-IrO2 was selected as the anode. The removal of sulfide by two-dimensional electrochemical oxidation followed zero-order kinetics, which was namely that residual sulfide concentration in solution had a linear relationship with time in all reaction stages. Sulfide existed in the form of HS in the solution. For the reason that H+ would be released when HS was oxidized, it was necessary to select a suitable initial pH and control the reaction time. The sulfide removal ratio and corresponding energy consumption of simulated gas field produced water with 300 mg/L sulfide and 2.50% (mass fraction) NaCl were above 99.2% and 55.2 kW·h (calculated by S2− of per kilogram), respectively, with the electrode distance of 5 cm, current density of 200 A/m2, aeration rate of 1 L/min, the initial pH of 9−10, and running time of 35 min. Moreover, reversing cathode and anode was found to effectively solve the problem of scaling on cathode caused by high Ca2+ and Mg2+ concentration.

       

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