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    陈学谦, 贺黎明, 曹伟, 朱云霞. 氦原子Rydberg态1D-3D谱项分裂值的多体微扰计算[J]. 华东理工大学学报(自然科学版), 2004, (6): 706-708711.
    引用本文: 陈学谦, 贺黎明, 曹伟, 朱云霞. 氦原子Rydberg态1D-3D谱项分裂值的多体微扰计算[J]. 华东理工大学学报(自然科学版), 2004, (6): 706-708711.
    CHEN Xue-qian, HE Li-ming~*, CAO Wei, ZHU Yun-xia. MBPT Calculation of 1D-3D Splittings in Helium Rydberg States[J]. Journal of East China University of Science and Technology, 2004, (6): 706-708711.
    Citation: CHEN Xue-qian, HE Li-ming~*, CAO Wei, ZHU Yun-xia. MBPT Calculation of 1D-3D Splittings in Helium Rydberg States[J]. Journal of East China University of Science and Technology, 2004, (6): 706-708711.

    氦原子Rydberg态1D-3D谱项分裂值的多体微扰计算

    MBPT Calculation of 1D-3D Splittings in Helium Rydberg States

    • 摘要: 通过自洽迭代求解Hartree方程得到各组态下的轨道波函数。以此构造组态波函数为基矢,对氦Rydberg态1snd组态的^1D—^3D谱项分裂值进行了多体微扰计算,计算结果与实验结果符合得较好。对于由同科电子构成的组态,由于没有相应的^3D谱项,所以由此计算得到的二级以上单态、三重态的能级修正值是不对称的。

       

      Abstract: Self-consistent iteration of Hartree equation is used to obtain orbital wave functions for (different) configurations. These functions build up the basis for ~1D-~3D splittings MBPT calculation of helium 1snd Rydberg states, and the results agree well with the experiments. Due to the lack of ~3D terms in some configurations composed of equivalent electrons, the second- and higher-order corrections for ~1D are asymmetric to those for ~3D.

       

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