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    郭少华, 应圣康. α-甲基苯乙烯阴离子平衡聚合动力学及反应历程研究[J]. 华东理工大学学报(自然科学版), 1986, (3).
    引用本文: 郭少华, 应圣康. α-甲基苯乙烯阴离子平衡聚合动力学及反应历程研究[J]. 华东理工大学学报(自然科学版), 1986, (3).

    α-甲基苯乙烯阴离子平衡聚合动力学及反应历程研究

    • 摘要: 本文研究了以环已烷作稀释剂,n-BuLi引发α-甲基苯乙烯阴离子平衡聚合动力学和反应历程,获得了单量体和缔合体引发α-甲基苯乙烯聚合的增长反应速度常数和解聚反应速度常数及相应的活化能。

       

      Abstract: The kinetics of anionic equilibrium polymerization of a-methylstyrene, with n-BuLi as an initiator and cyclohexane as a diluent, was investigated. The mechanism of polymerization participated by both monomeric and associated reactive species was postulated. The rate constants of propagation and dcpolymerization as well as their energies of activation of respective species have been evaluated.

       

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