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    邱春亮, 沈春银, 张杨, 李宾, 戴干策. 碳纤维毡增强聚丙烯复合材料的力学性能[J]. 华东理工大学学报(自然科学版), 2015, (6): 729-735.
    引用本文: 邱春亮, 沈春银, 张杨, 李宾, 戴干策. 碳纤维毡增强聚丙烯复合材料的力学性能[J]. 华东理工大学学报(自然科学版), 2015, (6): 729-735.
    QIU Chun-liang, SHEN Chun-yin, ZHANG Yang, LI Bin, DAI Gan-ce. Mechanical Properties of Carbon Fiber-Mat Reinforced Polypropylene Composites[J]. Journal of East China University of Science and Technology, 2015, (6): 729-735.
    Citation: QIU Chun-liang, SHEN Chun-yin, ZHANG Yang, LI Bin, DAI Gan-ce. Mechanical Properties of Carbon Fiber-Mat Reinforced Polypropylene Composites[J]. Journal of East China University of Science and Technology, 2015, (6): 729-735.

    碳纤维毡增强聚丙烯复合材料的力学性能

    Mechanical Properties of Carbon Fiber-Mat Reinforced Polypropylene Composites

    • 摘要: 将长碳纤维开松针刺成毡,并通过双钢带压机制备了碳纤维毡增强聚丙烯复合材料(CFRPP),考察了碳纤维长度、含量、纤维毡的针刺及针刺类型、基体改性等因素对复合材料力学性能的影响,并对复合材料断面进行了扫描电镜观察以分析CFRPP界面结合情况。结果表明:实验范围内的纤维长度对碳纤维增强复合材料的力学性能基本没有影响;复合材料综合力学性能最佳的碳纤维质量分数约为30%;碳纤维毡经三角形针针刺后复合材料的拉伸性能得到较大幅度提高;相容剂马来酸酐接枝聚丙烯(MPP)能够改善碳纤维与聚丙烯的界面结合,提高复合材料的力学性能,其最适宜的相容剂MPP的质量分数约为20%;将长度为80 mm的碳纤维用三角针刺成毡后,以MPP改性的聚丙烯(wMPP=20%)浸渍制备得到碳纤维质量分数为30%的复合材料,拉伸强度为203.3 MPa,拉伸模量达16.6 GPa,弯曲强度为223.2 MPa,弯曲模量达到12.0 GPa,缺口冲击强度为752.2 J/m。

       

      Abstract: The long carbon fibers were opened and prepared for the fiber-mat by means of needling, and then were used to produce the carbon fiber-mat reinforced polypropylene composites(CFRPP) with continuous double steel belts press. Effects of the length of the carbon fiber, fiber content, needling and needling type, matrix modification on the mechanical property of the composite materials were discussed, and the surface properties of the composites were characterized by scanning electron microscopy(SEM). The results revealed that the fiber length had little influence on the mechanical properties of CFRPP within the experiment range. The carbon fiber content of composites with optimized comprehensive mechanical properties was about 30%. The tensile properties of composites were improved significantly when the carbon fiber was acupunctured by triangle needles. The compatilizer MPP can modify the interaction between carbon fiber and polypropylene, and thus improve the mechanical properties of composites. The optimized dosage of compatilizer MPP was about 20%. When the carbon fiber felt was made by triangle needling with fiber length of 80 mm and impregnated by polypropylene modified with 20% of MPP, the tensile strength of composite with fiber content of 30% reached 203.3 MPa, tensile modulus 16.6 GPa, flexural strength 223.2 MPa, flexural modulus 12.0 GPa, and the notched impact strength 752.2 J/m.

       

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