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    朱珍, 吴和融, 李世瑨. 热致型高分子的液晶度与结晶度[J]. 华东理工大学学报(自然科学版), 1991, (6).
    引用本文: 朱珍, 吴和融, 李世瑨. 热致型高分子的液晶度与结晶度[J]. 华东理工大学学报(自然科学版), 1991, (6).
    Liquid Crystallinity and Crystallinity of Thermotropic Polymers[J]. Journal of East China University of Science and Technology, 1991, (6).
    Citation: Liquid Crystallinity and Crystallinity of Thermotropic Polymers[J]. Journal of East China University of Science and Technology, 1991, (6).

    热致型高分子的液晶度与结晶度

    Liquid Crystallinity and Crystallinity of Thermotropic Polymers

    • 摘要: 利用解偏振光强(DLI)、广角X-射线衍射(WAXD)及密度测定等方法,对目前国内外尚有争议的聚合物液晶态相态系统进行了研究,就聚合物液晶相的均相异相问题提出了新的看法,认为聚合物液晶相仍是一个异相系统,但由于聚合物处于液晶态时,分子排列比较规整,加之其特殊的粘度特性,致使液晶体系中液晶的不完善程度较结晶的不完善程度小,也即液晶度高于结晶度,从而解释了聚合物由结晶态进入液晶态时解偏振光强突然增大的反常行为。

       

      Abstract: The phase state system of polymer liquid crystals was discussed with DLI, WAXD and density analysis. A new point of view about homo- or heterogeneous nature of liquid crystalline polymers was put forward. It was suggested that the liquid crystal phase of polymers is of heterogeneous nature and the liquid crystallinity is higher than the crystallinity. Thus, the unusual behavior of anisotrophy of polymers on heating was explained.

       

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