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    王雪秋, 吴和融, 李世瑨. 具有柔性间隔基团的主链型液晶聚合物相转变的统计热力学[J]. 华东理工大学学报(自然科学版), 1988, (2).
    引用本文: 王雪秋, 吴和融, 李世瑨. 具有柔性间隔基团的主链型液晶聚合物相转变的统计热力学[J]. 华东理工大学学报(自然科学版), 1988, (2).
    Statistical thermodynamic theory for the phase transition of the liquid crystalline polymers consisting of mesogenic units and flexible spacers in the main chains[J]. Journal of East China University of Science and Technology, 1988, (2).
    Citation: Statistical thermodynamic theory for the phase transition of the liquid crystalline polymers consisting of mesogenic units and flexible spacers in the main chains[J]. Journal of East China University of Science and Technology, 1988, (2).

    具有柔性间隔基团的主链型液晶聚合物相转变的统计热力学

    Statistical thermodynamic theory for the phase transition of the liquid crystalline polymers consisting of mesogenic units and flexible spacers in the main chains

    • 摘要: 本文提出了文题聚合物的模型。用统计热力学方法对其相转变进行了理论推导,得到有序度的方程:,清晰点T_c=-(2φ/k),其中φ是转换能参数,k是玻尔兹曼常数。当φ小于零时,聚合物才具有液晶行为。

       

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