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    陈聚珊, 翁惠新, 毛信军, 刘馥英. 胶质对渣油催化预处理过程的影响[J]. 华东理工大学学报(自然科学版), 1989, (3).
    引用本文: 陈聚珊, 翁惠新, 毛信军, 刘馥英. 胶质对渣油催化预处理过程的影响[J]. 华东理工大学学报(自然科学版), 1989, (3).
    Influence of Resin on ART Processing[J]. Journal of East China University of Science and Technology, 1989, (3).
    Citation: Influence of Resin on ART Processing[J]. Journal of East China University of Science and Technology, 1989, (3).

    胶质对渣油催化预处理过程的影响

    Influence of Resin on ART Processing

    • 摘要: 以添加不同胶质量的胜利减二线油为试验油品,采用长岭炼油厂提供的热载体,在固定流化床反应装置上对文题进行了考察,并用色谱、核磁共振和顺磁共振等方法测试了胶质的性质及反应前后试油性质的变化。实验结果表明,试验用胜利减渣的胶质平均分子式为C_(102)H_(147)S_(0.63)N_(1.68)的大分子化合物,由基本结构相类似的重复单元构成,为带有烷基侧链及环烷环的环数不等的缩合芳香环。胶质分子彼此互连,形成呈胶体状态的分散胶束。试油在渣油催化预处理过程中主要进行热裂化反应。由于胶质的胶束被破坏,发生解聚作用,裂解与缩合作用加剧。所以,随着油品胶质含量的增加,气体、焦炭的产率增加,液收率下降。同时,杂质脱除率(脱镍、脱残炭、脱硫和脱氮)也上升。胶质的引入有利于自由基的生成,加速了热裂化反应。

       

      Abstract: The Asphalt Residual Treatment Process (ART) has been studied. Some feedstocks consisting of vacuum gas oil and resin were used. The heat carrier adopted was produced by Chalin Refinery. The influence of resin on ART was examined in a fixed fluidized bed reactor. Chromatography, ~1H-NMR and EPR spectrometry were used to analyze the composition of feedstocks as well as products and to characterize the change of resin during the reaction.Experimental results showed that the average chemical formula for the resin can be expressed as C_(102)H_(147)S_(0.63)N_(1.68). These large molecules are formed by repeating unit of similar structure of different numbers of condensed aromatic rings with alkyl side chains or naphthene rings. The molecules of resin link each other to form a colloid with dispersed micelles.The feedstock was subjected to thermal cracking; with increasing resin content, the gas and coke yields increase, while that of liquid oil decreases, and the impurity removal percentage (removal of carbon, nickel, sulfur and nitrogen) increases. Addition of resin can promote the formation of free radicals and speed up the thermal cracking reaction.

       

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