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    宁方红, 刘坐镇, 诸蓓艳, 刘勤凤, 邬行彦, 王彬芳. 硼基亲和层析介质的合成及其应用研究 I.基质的合成及孔结构[J]. 华东理工大学学报(自然科学版), 1998, (5).
    引用本文: 宁方红, 刘坐镇, 诸蓓艳, 刘勤凤, 邬行彦, 王彬芳. 硼基亲和层析介质的合成及其应用研究 I.基质的合成及孔结构[J]. 华东理工大学学报(自然科学版), 1998, (5).
    Synthesis of the Media for the Boronate Affinity Choromatographic and Their ApplicationsI. Studied on the Synthesis and Structure of the Matrix[J]. Journal of East China University of Science and Technology, 1998, (5).
    Citation: Synthesis of the Media for the Boronate Affinity Choromatographic and Their ApplicationsI. Studied on the Synthesis and Structure of the Matrix[J]. Journal of East China University of Science and Technology, 1998, (5).

    硼基亲和层析介质的合成及其应用研究 I.基质的合成及孔结构

    Synthesis of the Media for the Boronate Affinity Choromatographic and Their ApplicationsI. Studied on the Synthesis and Structure of the Matrix

    • 摘要: 以甲基丙烯酸缩水甘油酯和二甲基丙烯酸乙二醇酯为原料,合成了大孔树脂,并研究了交联度、混合致孔剂用量和配比对其孔结构的影响。该树脂与间氨基苯硼酸偶联,制得硼基-聚甲基丙烯酸缩水甘油酯共价亲和层析介质,介质的硼基偶联量可达1.036mmol/g。

       

      Abstract: The macroreticular resin was preparted by the copolymerization of glycidyl methacrylate (GMA) with ethylene dimethacrylate(EDMA) and its pore structure was determined. The effects of the ammount of crosslinking degree and the amount as well as proportion of the mixed diluent on the pore structure were also investigated. The matrix of boric acid substituted PGMA covalant affinity chromatographic were prepared using the PGMA copled with m aminophonyl boronic acid and the capacity of the banic acid of the matrix was up to 1.036mmol/g.

       

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