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    张敏娟, 余芳芳, He Helen Song, Kwong Cathy KarWing, 施敏, Toy Patrick H. 聚苯乙烯负载的奎宁环催化剂的合成[J]. 华东理工大学学报（自然科学版）, 2009, (1): 80-84.
    引用本文: 张敏娟, 余芳芳, He Helen Song, Kwong Cathy KarWing, 施敏, Toy Patrick H. 聚苯乙烯负载的奎宁环催化剂的合成[J]. 华东理工大学学报（自然科学版）, 2009, (1): 80-84.
    shu
    Synthesis of Polystyrene-Supported Quinuclidine and Its Use as Catalyst for Morita-Baylis-Hillman Reactions[J]. Journal of East China University of Science and Technology, 2009, (1): 80-84.
    Citation: Synthesis of Polystyrene-Supported Quinuclidine and Its Use as Catalyst for Morita-Baylis-Hillman Reactions[J]. Journal of East China University of Science and Technology, 2009, (1): 80-84.
    shu

    聚苯乙烯负载的奎宁环催化剂的合成

    Synthesis of Polystyrene-Supported Quinuclidine and Its Use as Catalyst for Morita-Baylis-Hillman Reactions

      摘要
    • 摘要: 通过3-(4-乙烯基苄氧基)-1-氮杂-双环［2,2,2］辛烷和苯乙烯共聚合制备聚(苯乙烯-共-3-(4-乙烯基苄氧基)-1-氮杂-双环［2,2,2］辛烷)，并将其作为非均相催化剂应用于分子内和分子间的Morita-Baylis-Hillman及氮杂-Morita-Baylis-Hillman反应中，在所有这些反应中，产物的产率都可达到中等水平。

       

      Abstract: Poly(styrene-co-3-(4-vinylbenzyloxy)-1-aza-bicyclo［2,2,2］octane) was prepared by the copolymerization of 3-(4-vinylbenzyloxy)-1-aza-bicyclo［2,2,2］octane and styrene. This supported tertiary amine was used as a heterogeneous catalyst in both intra and intermolecular Morita-Baylis-Hillman and aza-Morita-Baylis-Hillman reactions. The products of all the reactions can achieve middle-level yields.

       

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