锐钛型TiO_2性能研究 Ⅱ.锐钛型TiO_2的光化学活性封闭及其表征
Study on the Properties of Anatase TiO2\= II.The Dense Coat and Characterization of Photochemical \= Activity of Anatase TiO2
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摘要: 用水热法SiO2致密包覆封闭锐钛型TiO2表面的光化学活性点,以Cr2O2-7的还原反应考察包覆层的致密性及包覆效果。讨论了TiO2浆液的浓度、温度、pH及保温熟化等反应条件对SiO2致密包覆的影响。Abstract: The hydrothermal surface modification with silica is applied to dense coat surface photochemical activity of anatase TiO2. The reducing reaction of Cr2O2-7 is used to evaluate the integrity of the coating layer, and TEM is used to inspect its surface state. Some factors, e.g., TiO2 slurry solid concentration, temperature, pH as well as reaction time, which dominate the dense coat were studied.