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    张丹枫1, 赵平1, 黄葆同1, 2. N-(2,6-二烷基苯基)-2-呋喃甲酰胺镍配合物的合成及其催化甲基丙烯酸甲酯的聚合[J]. 华东理工大学学报（自然科学版）, 2012, (1): 1-5.
    引用本文: 张丹枫1, 赵平1, 黄葆同1, 2. N-(2,6-二烷基苯基)-2-呋喃甲酰胺镍配合物的合成及其催化甲基丙烯酸甲酯的聚合[J]. 华东理工大学学报（自然科学版）, 2012, (1): 1-5.
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    ZHANG Dan-feng1, ZHAO Ping1, HUANG Bao-tong1, 2. Synthesis of N-(2,6-Dialkylphenyl)-2-Furoamide Ni Complex and Its Catalytic Behavior for Polymerization of Methyl Methacrylate[J]. Journal of East China University of Science and Technology, 2012, (1): 1-5.
    Citation: ZHANG Dan-feng1, ZHAO Ping1, HUANG Bao-tong1, 2. Synthesis of N-(2,6-Dialkylphenyl)-2-Furoamide Ni Complex and Its Catalytic Behavior for Polymerization of Methyl Methacrylate[J]. Journal of East China University of Science and Technology, 2012, (1): 1-5.
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    N-(2,6-二烷基苯基)-2-呋喃甲酰胺镍配合物的合成及其催化甲基丙烯酸甲酯的聚合

    Synthesis of N-(2,6-Dialkylphenyl)-2-Furoamide Ni Complex and Its Catalytic Behavior for Polymerization of Methyl Methacrylate

      摘要
    • 摘要: 以呋喃甲酸、5叔丁基2呋喃甲酸为起始物，在PCl3作用下，与苯胺、2, 6二烷基苯胺反应（烷基为乙基、异丙基），合成了4个N(2, 6二烷基苯基)5叔丁基2呋喃甲酰胺有机配体，同时以N(2, 6二乙基苯基)5叔丁基2呋喃甲酰胺与trans［NiCl(Ph)(PPh3)2］反应合成了1个新的呋喃甲酰胺镍配合物，并采用核磁共振（1HNMR）、红外光谱（IR）、质谱（MS）及元素分析（EA）对它们的结构进行了表征。以该配合物为催化剂，在甲基铝氧烷（MAO）作用下对甲基丙烯酸甲酯进行了催化聚合，以配合物中等的催化活性得到了富含间规结构的聚甲基丙烯酸甲酯（PMMA）。

       

      Abstract: Under the effect of PCl3, four compounds of N(2, 6dialkylphenyl)5butyl2furoamides (alkyl: ethyl, isopropyl) were synthesized by reaction of 3furoic acid, 5butyl2furoic acid with aniline, 2, 6dialkyl aniline, respectively. A novel nickel complex, N(2, 6diethylphenyl)5butyl2furoamide Ni(Ph)(PPh3) was prepared via corresponding ligand and trans［NiCl(Ph)(PPh3)2］. The structures of furoamide compounds and the Ni complex were characterized by 1HNMR， IR, MS and EA. In the presence of methylaluminoxane (MAO) as cocatalyst, the nickel complex exhibited a mediate activity for the polymerization of methyl methacrylate (MMA) and syndiotacticrich poly(methyl methacrylate) was obtained.

       

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