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    吕露, 王绍华, 易红玲, 公维光, 林珩, 郑柏存. 杂化硅溶胶/有机硅低聚物复合透明超疏水涂层的制备及性能[J]. 华东理工大学学报(自然科学版), 2021, 47(2): 147-153. DOI: 10.14135/j.cnki.1006-3080.20191202002
    引用本文: 吕露, 王绍华, 易红玲, 公维光, 林珩, 郑柏存. 杂化硅溶胶/有机硅低聚物复合透明超疏水涂层的制备及性能[J]. 华东理工大学学报(自然科学版), 2021, 47(2): 147-153. DOI: 10.14135/j.cnki.1006-3080.20191202002
    LYU Lu, WANG Shaohua, YI Hongling, GONG Weiguang, LIN Heng, ZHENG Baicun. Preparation and Properties of Hybrid Silica Sol/Organsilicon Oligomer Composite Transparent Superhydrophobic Coatings[J]. Journal of East China University of Science and Technology, 2021, 47(2): 147-153. DOI: 10.14135/j.cnki.1006-3080.20191202002
    Citation: LYU Lu, WANG Shaohua, YI Hongling, GONG Weiguang, LIN Heng, ZHENG Baicun. Preparation and Properties of Hybrid Silica Sol/Organsilicon Oligomer Composite Transparent Superhydrophobic Coatings[J]. Journal of East China University of Science and Technology, 2021, 47(2): 147-153. DOI: 10.14135/j.cnki.1006-3080.20191202002

    杂化硅溶胶/有机硅低聚物复合透明超疏水涂层的制备及性能

    Preparation and Properties of Hybrid Silica Sol/Organsilicon Oligomer Composite Transparent Superhydrophobic Coatings

    • 摘要: 以气相纳米二氧化硅、正硅酸乙酯(TEOS)和六甲基二硅氮烷(HMDS)为原料,采用溶胶-凝胶法制备杂化硅溶胶,将γ-(2,3-环氧丙氧)丙基三甲氧基硅烷(KH560)和烷基硅氧烷制备的有机硅低聚物与杂化硅溶胶复合得到透明超疏水涂层,研究了气相纳米二氧化硅、HMDS和KH560用量以及烷基硅氧烷种类对复合涂层性能的影响。结果表明:当气相纳米二氧化硅与TEOS的质量比为0.075,HMDS与TEOS的质量比为0.75,烷基硅氧烷为甲基三乙氧基硅烷(MTES),且KH560和MTES的物质的量之比为0.50,有机硅低聚物与杂化硅溶胶质量比为0.100时,制备的涂层接触角可达165°,具有优异的超疏水性能和良好的附着力、坚固性以及高透光率。

       

      Abstract: Transparent superhydrophobic coatings have potential applications in optical devices, solar panels, automobile windshields and glass building facade. However, their real-world applications are restricted by low transparency, poor durability, and the complex preparation processes. Hybrid silica sol is commonly prepared by the sol-gel process using fumed silica, tetraethoxysilane (TEOS) and hexamethyl-disilazane (HDMS) as raw materials. In this study, transparent superhydrophobic composite coatings were obtained via incorporating the hybrid silica sol with organosilicon oligomer synthesized from 2,3-epoxypropoxy propyltrimethoxysilicane (KH560) and alkyl siloxane as precursors. The influence of loading of fumed silica and HDMS on the hydrophobic property of the hybrid silica sol coatings was investigated, and the effects of KH560 , organosiloxane diversity and organosilicon oligomer loading on the properties of composite coatings were studied. The optimal performance of hybrid silica sol coatings was obtained with a water contact angel (CA) of 166° and sliding angel (SA) of less than 3° when the mass ratio of nano-fumed silica to TEOS was 0.075, and the mass ratio of HMDS to TEOS was 0.75, respectively. When the molar ratio of KH560 to MTES was up to 0.50, and the mass ratio of organosilicon oligomer to hyrid silica sol was 0.100, the composite coating remained superhydrophobic with water contact angle being 138° even after ultrasonic treatment for 5 min. Scanning electron microscopic showed a continuous porous network with a large amount of micro-nano composite rough structures on the surface of the composite coating. Furthermore, the optical transmittance of the hybrid silica superhydrophobic composite coating reached 85.4% at 550 nm.

       

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