Abstract:
Li
2SiO
3:Eu
3+ phosphor precursor was prepared via a simple ball-grinding solid state reaction at room temperature using LiOH·H
2O,Si(OC
2H
5)
4 and Eu(NO
3)
3·6H
2O as raw materials,then after calcination at high temperature,a series of Li
2SiO
3:
x% Eu
3+ red phosphors were obtained.The influences of calcining temperature,dwelling time and Eu
3+ contents on the structure and luminescent properties of as-prepared phosphors were investigated.The results indicated that the phase composition of Li
2SiO
3:
x% Eu
3+ did not change with the increase of Eu
3+ content when
x was in the range of 1.5 to 15,and the concentration quenching phenomenon did not appear until the value of
x reached 12.When the calcining temperature was 1 173 K and the dwelling time was 2 h,the luminous intensity of the fluorescent system reached the maximum value.The Li
2SiO
3:Eu
3+ phosphors showed an intense red emission,corresponding to the
5D
0→
7F
2 (615 nm) transition of Eu
3+under 467 nm excitation.